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三羟丙烷的合成、用途以及使用注意

发布来源:http://www.jinhao360.com    更新时间:2023-02-14 点击数:57

三羟甲基丙烷(简称TMP),白色片状结晶。易溶于水、低碳醇、甘油、N,N-二甲基甲酰胺,部分溶于丙酮、乙酸乙酯,微溶于四氯化碳、乙醚和氯仿。主要用于醇酸树脂、聚氨酯、不饱和树脂、聚酯树脂、涂料等领域,也可用于合成航空润滑油、印刷油墨等,还可用作纺织助剂和聚氯乙烯树脂的热稳定剂。
Trimethylolpropane (TMP), white flake crystal. Easily soluble in water, lower alcohol, glycerin, N, N-dimethylformamide, partially soluble in acetone and ethyl acetate, slightly soluble in carbon tetrachloride, ether and chloroform. It is mainly used in alkyd resin, polyurethane, unsaturated resin, polyester resin, coating and other fields. It can also be used to synthesize aviation lubricating oil, printing ink, etc. It can also be used as textile auxiliaries and heat stabilizer of PVC resin.
合成方法
synthetic method 
正丁醛与甲醛在碱性性条件下进行缩合反应,反应液经浓缩除盐,再用离子交换树脂脱色,提纯,后用薄膜蒸发器蒸发、冷却、轧片,得成品。
The condensation reaction of n-butyraldehyde and formaldehyde is carried out under alkaline conditions. The reaction solution is concentrated and desalted, then decolored and purified with ion exchange resin, and then evaporated, cooled and rolled with a film evaporator to obtain the finished product.
主要用途
Main purpose
三羟甲基丙烷是一种重要的精细化工产品,它是树脂行业常用的扩链剂。其熔点低,分子结构中有3个羟甲基,可与有机酸反应生成单酯或多酯,与醛、酮反应生成缩醛、缩酮,与二异氰酸酯反应生成氨基甲酸酯等。
Trimethylolpropane is an important fine chemical product. It is a chain extender commonly used in the resin industry. It has a low melting point and three hydroxymethyl groups in its molecular structure. It can react with organic acids to form monoesters or polyesters, react with aldehydes and ketones to form acetals and ketals, and react with diisocyanates to form carbamates.
三羟甲基丙烷
产品主要用于醇酸树脂、聚氨酯、不饱和树脂、聚酯树脂、涂料等领域,也可用于合成航空润滑油、增塑剂、表面活性剂、润湿剂、炸药、印刷油墨等,还可用作纺织助剂和聚氯乙烯树脂的热稳定剂。
The products are mainly used in alkyd resin, polyurethane, unsaturated resin, polyester resin, coating and other fields, and can also be used to synthesize aviation lubricating oil, plasticizer, surfactant, wetting agent, explosive, printing ink, etc., and can also be used as textile auxiliaries and thermal stabilizer of PVC resin.
应急处理
Emergency Management
隔离泄漏污染区,限制出入。切断火源。建议应急处理人员戴防尘面具,穿一般作业工作服。用砂土、干燥石灰或苏打灰混合。收集于干燥、洁净、有盖的容器中,转移场所。若大量泄漏,收集回收或运废物处理场所处置。
Isolate the contaminated area and restrict access. Cut off the ignition source. It is recommended that emergency personnel wear dust masks and general work clothes. Mix with sand, dry lime or soda ash. Collect in a dry, clean and covered container and transfer to a safe place. If there is a large amount of leakage, it shall be collected and recycled or transported to the waste treatment site for disposal.
储运特性
Storage and transportation characteristics
1.操作注意事项。密闭操作,加强通风。操作人员须经过专门培训,严格遵守操作规程。建议操作人员佩戴自吸过滤式防尘口罩。远离火种、热源,工作场所严禁吸烟。使用防爆型的通风系统和设备。避免与氧化剂、酸类接触。搬运时轻装轻卸,防止包装破损。配备相应品种和数量的消防器材及泄漏应急处理设备。倒空的容器可能残留有害物。
1. Precautions for operation. Close operation and strengthen ventilation. Operators must receive special training and strictly abide by the operating procedures. It is recommended that operators wear self-priming filter dust masks. Keep away from kindling and heat sources. Smoking is strictly prohibited in the workplace. Use explosion-proof ventilation system and equipment. Avoid contact with oxidants and acids. Handle with care to prevent package damage. Provide fire fighting equipment and leakage emergency treatment equipment of corresponding types and quantities. Empty containers may contain harmful substances.
2.储存注意事项。储存于阴凉、通风的库房。远离火种、热源。应与氧化剂、酸类分开存放,切忌混储。配备相应品种和数量的消防器材。储区应备有合适的材料收容泄漏物。
2. Precautions for storage. Store in a cool and ventilated warehouse. Keep away from kindling and heat sources. It shall be stored separately from oxidants and acids, and mixed storage is prohibited. Provide fire fighting equipment of corresponding types and quantities. The storage area shall be equipped with appropriate materials to contain the leakage.
起运时包装要完整,装载应稳妥。运输过程中要确保容器不泄漏、不倒塌、不坠落、不损坏。严禁与氧化剂、酸类等混装混运。运输途中应防曝晒、雨淋,防高温。更多相关产品的信息就来我们网站http://www.jinhao360.com咨询吧!
The package shall be complete and the loading shall be stable when shipping. During transportation, ensure that the container does not leak, collapse, fall or damage. It is forbidden to mix and transport with oxidants, acids, etc. During transportation, it shall be protected from sunshine, rain and high temperature. For more information about related products, please visit our website http://www.jinhao360.com Ask!

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